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Chemistry 346 Physical Chemistry II

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Chemistry 346 Physical Chemistry II

College Of Liberal Arts And Sciences

Spectroscopy, Selection Rules

March 27, 2024

Spectroscopy Selection Rules

Reading

Ch. 15 of "Free Energy" pgs. 412-414

Lectures, Discussions, Labs

Final Exam Review
Summary of Physical Chemistry
Enzyme Kinetics
Exam 3 Review
Kinetics: Consecutive Reactions and Equilibrium
Kinetics Pt. 2: Reaction Mechanisms
Introduction to Kinetics
UV/Vis Spectroscopy and Molecular Orbitals
Spectroscopy: Rotation and Vibration
The Electromagnetic Spectrum
Why Everything You Learned is a Lie
Exchange, Magnetism and Spin-Orbit Coupling
Spin States and the Exchange Interaction
Multielectron Atoms, Shielding and the Pauli Principle
Quantum Matrix Mechanics
Spectroscopy, Selection Rules
Hydrogen P, D States and Spin-Orbit Interactions
Hydrogen Radial Wavefunctions
HW 8 Review Session
Separability of the Hydrogen Atom Hamiltonian Pt. II
Separability of the Hydrogen Atom Hamiltonian
Exam2 Review
3D Rigid Rotor Wavefunctions and Spin
The 2D Rigid Rotor
Rotation in 3D
Multidimensional Quantum Mechanics and Intro to Rotation
The Uncertainty Principle Pt. 2
The Uncertainty Principle Part 1
Practice problems
The Harmonic Oscillator Pt. II, Turning Points
The Harmonic Oscillator Pt. I: Vibrational Wavefunctions
Practice Problems
Particle in an Infinite vs. Finite Box
Reflection off a Barrier and Tunneling Phenomena
Freewaves and Barrier Potentials
Exam 1 Review
Proof of the Expectation Value Equation
Operators and Eigenvalue Equations
Expectation (i.e. Average) Values
All About Wavefunctions
Introduction to the Schrodinger Equation
The Planck Distribution
Review of Boltzmann Statistics and Probability Distribution Function Engineering
Light Waves in a Box!
The Photoelectric Effect and Introduction to Blackbody Radiation
Relative Velocity, Collision Frequency and Flux
Transformation of variables in integrals via the Jacobian
Velocities!
The Maxwell-Boltzmann Distribution of Velocity
The Erf() Function and Integral Substitution of Variables
Introduction to the Maxwell-Boltzmann Distribution
Introduction to Probability Distributions

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Dept. of Chemistry, 845 W. Taylor St., Chicago, IL 60607

Phone: (312) 413-2566

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